Confirmed,[DS] Set The Path&Under Investigation,We Can Now Do Things That Were Not Possible – Ep. 3200 (2024)

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Ep 3200a – Founding Fathers, Abraham Lincoln Warned Us, [CB] The Target

The installed leaders are now rolling back or backtracking on the green new deal, why? The people are awake and they see what they are trying to do. The economy has failed many of the people and the people are getting pissed off at the Bide admin/Fed etc. The [CB] is the target, Abraham Lincoln warned us about the [CB]. The [DS] is now setting the precedent that Trump can use against them later on. The [DS] is being investigated by military intelligence. Soon the patriots will be able to do everything they are doing to Trump to them. Trump will be able to do things that were not possible. The people will be with him, the people will want peace.

Economy

Canada’s Trudeau the Latest Leader to Backtrack and Delay on Climate Alarmist Policies – Rolls Back Home Heating Oil Carbon Tax for 3 Years

  • About a month ago, British Prime Minister Rishi Sunaktook a hint from brutal opinion pollsand decided to put his citizens financial welfare ahead of the crazy climate alarmist policies that every good Globalist has to follow to the letter.
  • Outrage ensued, as you would expect – but the trend now seems to be catching on.
  • Now it’s Canadian Prime Minister Justin Trudeau – who just announced a three-year carbon tax exemption for home heating oil, also and higher carbon tax rebates for people in rural areas.
  • These measures are intended to bring economic relief to families, amid high costs of living.
  • Lawmakers in his own Liberal party have strenuously called for changes to pricing on carbon ‘to combat climate change’, in particular in the Atlantic Canada region.
  • Reutersreported:
  • “‘After plummeting in the polls, a flailing, desperate Trudeau is now flipping and flopping on the carbon tax as I am holding a gigantic axe the tax rally in a Liberal-held Atlantic riding’, Conservative leader Pierre Poilievre wrote on social media platform X.”
  • Conservatives are, of course, doing a victory lap out of Trudeau’s change of course.
  • National Observerreported:
  • “After four years of defending the carbon tax, Justin Trudeau’s government crashed into the political reality unfolding in Atlantic Canada

Source: thegatewaypundit.com

Good Morning Everyone! McDonald’s beats earnings expectations in Q3.

Why? Price hikes (inflation).

EPS was up +19% and revenue was up +14% YoY.

Fast food chains will likely continue to do well as the economy slows.

Sadly, when times are tough, people choose cheaper but less… pic.twitter.com/x6AuOIHhEh

— Genevieve Roch-Decter, CFA (@GRDecter) October 30, 2023

healthy foods.

Here it comes … 🔥🔥🔥

Fast food minimum wage of $20 per hour makes other options more viable for businesses. pic.twitter.com/OinOsMPYOU

— Wall Street Silver (@WallStreetSilv) October 30, 2023

Wait till they use income to decide what the rates are – the poor get subsidized cheap electricity as a "human right", meanwhile the middle class and the rich get hit with double or triple the electricity rates to pay for it all.

🔥🔥🔥 pic.twitter.com/UAzyy7Y6cl

— Wall Street Silver (@WallStreetSilv) October 30, 2023

Survey Found Most Americans Falling Behind On Emergency Savings

  • A large majority of Americans are falling behind on their savings, as 81 percent have not increased their emergency savings since the beginning of the year, according to a survey.
  • The survey byBankrate, released on Oct. 25, showed just 19 percent of American households increased their emergency savings, while32 percent have less savings now compared with the beginning of 2023. Thirty percent of households have the same amount of savings, while 20 percent had no emergency savings at the start of the year and remain having none.
  • In terms of age, older generations tend to have less emergency savings now than at the beginning of the year.
  • According to the survey, households with income over $100,000 tend to have more savings now than at the beginning of the year.
  • In addition, the survey found that 60 percent of Americans are falling behind on their savings for emergencies, in which 38 percent said they are significantly behind and 22 percent said they are slightly behind.

Source: zerohedge.com

The US national debt is growing faster than the economy, per CNBC: pic.twitter.com/HDXk37wRmg

— unusual_whales (@unusual_whales) October 29, 2023

Political/Rights

CBS Reporter Catherine Herridge Faces Contempt Charges For Refusing to Reveal Her Confidential Source

  • CBS reporter Catherine Herridge is facing contempt charges for refusing to disclose the identity of her confidential source.
  • In August, US District Court for the District of Columbia, Christopher Cooper, ordered Herridge to sit down for a sworn deposition regarding a confidential source she used for a2017 storyshe covered on a Department of Defense-funded school that was at the center of federal investigations over Chinese military ties while she was at Fox News.
  • The judge ordered Herridge to turn over her source(s) in response to a lawsuit that was filed by Chinese-American scientist Yanping Chen against the FBI. Chen subpoenaed Herridge in an effort to find out who her sources were.
  • Herridge argued she should not be forced to disclose her source because of her First Amendment rights.
  • Judge Cooper, an Obama appointee, disagreed and forced Herridge to unmask her source.

  • “The Court recognizes both the vital importance of a free press and the critical role that confidential sources play in the work of investigative journalists like Herridge,” Cooper wrote in therulingin August. “But applying the binding case law of this Circuit, the Court concludes that Chen’s need for the requested evidence overcomes Herridge’s qualified First Amendment privilege in this case.”
  • Herridge refused to disclose her source during the deposition and now she faces contempt charges and potential jail time, The Epoch Timesreported.
  • Source: thegatewaypundit.com

🚨

Obama DC U.S. District Judge Christopher Cooper, whose wife was a Clinton & Obama political appointee and Eric Holder's national-security counsel, sided with an alleged Chinese agent.

Judge Cooper ordered a former Fox and current CBS reporter to reveal her sources.… https://t.co/zCZRd9MyrQ

— 🇺🇸 Mike Davis 🇺🇸 (@mrddmia) October 30, 2023

  • Outrageous assault on free press. Naturally, crickets from “mainstream” (liberal) reporters, who are too blinded by ideology to realize they could be next. The DC Circuit is stacked with Obama judges. Will the Supreme Court have the courage to stop these Republic-ending attacks by Democrat attorneys, prosecutors, and judges?

EXCLUSIVE: DoJ officials are accused of spying on watchdogsJason Foster and Kash Patel who were overseeing Crossfire Hurricane investigation into Trump-Russia collusion

  • Congressional lawyersJason Foster and Kash Patel say DoJ secretly subpoenaed their phone records while they were overseeing Crossfire Hurricane
  • Foster told DailyMail.com he got an email from Google revealing the DoJ requested his Google Voice records between December 1, 2016 and May 1, 2017
  • Patel is now suing the Justice Department claiming it violated constitutional protections in a ‘blatant abuse’ of power
  • The Department of Justice illegally surveilled congressional lawyers in a ‘blatant abuse’ of power, according to the targets of the newly revealed snooping.
  • Top GOPcongressionallawyers were investigating the Justice Department in 2017 over its controversial Russian collusion probe, codenamed‘Crossfire Hurricane’.
  • But new documents reveal that at the same time, the DoJ office they were probing was spying on their phone calls and emails in an allegedly illegal ‘fishing expedition’.
  • one of the key players in the scandalous surveillance was Tejpal Chawla, a federal prosecutor who has donated to Democratcampaigns.
  • One of thecongressionallawyers targeted by Chawla’s snooping is now demanding documents from the DoJ, and another is suing the Department claiming it violated constitutional protections in a ‘blatant abuse’ of power.
  • In 2017, Chawla, an Assistant US Attorney in the Washington DCUS Attorney’s office, subpoenaed phone records of lawyers working for theSenateand House.
  • His snooping subpoena came just as those Congressional staffers were investigating Chawla’s office over its ‘Crossfire Hurricane’ probe, which alleged collusion between Russian agents andDonald Trump‘s presidential campaign.

    Source:dailymail.com

    Michael Flynn, who Trump says would have a prominent position in his next Admin, says that members of the House and Senate are compromised by globalists who have blackmail on them because they had sex with children. pic.twitter.com/TgA6muk888

    — Ron Filipkowski (@RonFilipkowski) October 29, 2023

    REVEALED: Migrants in New York City hotels and shelters are costing the taxpayer $5BILLION: Eyewatering contracts show $140m is being spent on security, $45m on asylum applications and $7m on laundry

    • NYC has spent billions setting up emergency shelters across the five boroughs
    • More than 120,000 migrants have arrived in the city in the last 18 months
    • Mayor Adams has said the crisis will cost the town $12billion over three years
    • New York Cityhas signed nearly 200 eyewatering emergency contracts totaling over $5billion to house and care for migrants, paying as much as $140M for security, $45million in legal aid services and $7million in laundry.
    • Mayor Eric Adams has signed $5,056,744,415 in nearly 200 contracts for migrant services since last year, when he declared a state of emergency, allowing City Hall to bypass a competitive bidding process to address the surge of asylum seekers.

    Source: dailymail.co.uk

    Everything is fine … 🔥🔥🔥

    Why is the Biden Administration allowing this? Are they not at all concerned about this? pic.twitter.com/dLqz3vF5cB

    — Wall Street Silver (@WallStreetSilv) October 30, 2023

    Geopolitical/Police State

    • YouTube, has decided to suspend the Los Angeles Police Department’s channel. The suspension was triggered by the LAPD’s decision to share footage of an assault, aimed at garnering the community’s assistance in identifying the involved suspects.

    Confirmed,[DS] Set The Path&Under Investigation,We Can Now Do Things That Were Not Possible – Ep. 3200 (4)

    • The altercation that led to the suspension occurred on September 28. The footage captured an unsettling scene near Speedway and Market Street, where a male victim had a chance encounter with two individuals armed with bicycles.
    • Out of the blue, one of the bicycle riders brandished a pair of bolt cutters, using them to launch a barrage of attacks—both punching and kicking—against the unsuspecting victim. After a brief hiatus, the attacker returned to deliver a final blow, knocking the victim unconscious with the same bolt cutters.
    • What was intended to be a genuine plea for public assistance has now evolved into a much larger discussion about digital platforms and their powers to disrupt police and community appeals.

    Source: reclaimthenet.net

    Maine Law Enforcement Received Statewide Alert on ‘Veiled Threats’ by Army Reservist Robert Card Weeks Prior to Bowling Alley and Bar Massacre that Left 18 Dead, 13 Injured

    • law enforcement agencies in Maine had been alerted weeks before the incident about “veiled threats” made by Card.
    • Accordingto the News Center Maine, Sagadahoc County Sheriff Joel Merry had sent deputies to Card’s home in September after receiving a tip from the U.S. Army Reserve that Card had issued “veiled threats” against an Army base.
    • Authorities were unable to locate him, and they moved on.
    • “We couldn’t locate him,” Merry said, adding that he couldn’t recall if there was any follow-up.
    • An “awareness alert” was then sent to all of the state’s law enforcement agencies.
    • Saco Police Chief Jack Clements even deployed officers to patrol the local Army base where Card had trained, but they also came up empty-handed.
    • “We added extra patrols, we did that for about two weeks. … The guy never showed up,” said Jack Clements.
    • Despite the alerts and the efforts to locate him, Card was not on the FBI’s radar before the shootings.
    • He was committed to a mental health facility, Keller Army Community Hospital at West Point, for two weeks, but it appears that this did not put him on the radar of law enforcement agencies.
    • Spectrum Newsreported:

    Source: thegatewaypundit.com

    JUST IN: Police visited Maine gunman's home SIX WEEKS before massacre after he told doctors he was going to 'SNAP AND COMMIT a mass shooting.'

    Law enforcement chiefs in Maine issued an awareness alert for Robert Card, a U.S. Army reservist, in September after threats were made.… pic.twitter.com/BgL27DkuKn

    — Chuck Callesto (@ChuckCallesto) October 30, 2023

    Despite visits and increased patrols, Card remained elusive. During a welfare check, it was noted that he typically answered the door with a concealed handgun.

    David Hogg Now Blames “White Woman In Suburbs” For Gun Violence

    “We will never end gun violence until white woman in the suburbs stop voting for the republicans who are endangering our schools and communities by flooding them with guns.”

    We will never end gun violence until white woman in the suburbs stop voting for the republicans who are endangering our schools and communities by flooding them with guns.

    — David Hogg 🟧 (@davidhogg111) October 27, 2023

    • Hogg is not ready for this conversation, as his bigotry against white women in the suburbs is uncalled for as a recent poll fromNYPost, citing Wallet Hub data, shows murder rates in Democratic areas, including Memphis, Tennesse; New Orleans, Louisana; Richmond, Virginia; Washington, DC; and Detroit, Michigan, with soft-on-crime policies, are surging.
    Confirmed,[DS] Set The Path&Under Investigation,We Can Now Do Things That Were Not Possible – Ep. 3200 (5)
    • As for those white women in suburbia (in fact, any woman of any race) – they have a God-given right to use reasonable force, including deadly force, to protect their families and themselves against an intruder in their home – especially since the average police response time in suburbia can be ten minutes or more.
    • Wow, we just went from “It’s the guns” to “It’s the white women in suburbs”…that escalated quickly.

    let’s look at where the violence is being committed

    — Garand Thumb (@GarandThumb1) October 27, 2023

    Source:zerohedge.com

    Why did we leave all of the equipment there? Was it just a quick exit and they didn't have time? or was it intentionally done for a purpose?

    Was the purpose to destabilize the region? Have them equipped? Did Biden's people know that a lot of the equipment would be sold on the… https://t.co/7McU7hQJyR

    — Wall Street Silver (@WallStreetSilv) October 30, 2023

    the black market? or they were just clueless? Sometimes it makes you wonder? Are they doing it all on purpose or are they just clueless?

    Always remember the United States is the only country with a First Amendment and also the only country with a Second Amendment.

    For all its flaws, Reagan was absolutely right when he said "If we lose freedom here, there is no place to escape to. This is the last stand on earth." https://t.co/UMAxIUCHF8

    — Hans Mahncke (@HansMahncke) October 30, 2023

    Gun Sales Spike 200% in Maine After Tragic Mass Shooting

    • Gun sales in Lewiston, Maine and the surrounding area spiked over 200% after a deadly mass shooting claimed the lives of 18 people and wounded over a dozen more.
    • Despite a shelter-in-place order being put in place in Lewiston, Maine, local gun shop owners were urged to open up their doors by community members who pleaded with them to open up shop.
    • According toFox Business, Ryan Gagnon, who is a co-owner of 3 Cousins Firearms in Lewiston, reported, “Our sales were up, I would say, over 200% compared to a typical Friday.”
    • Another gun shop owner, Tony Lewis, shared that he did more business after the mass shooting than he did the entire month.

    Source: thegatewaypundit.com

    War

    Another Political Assassination Attempt – Pro-Russia Politician Oleg Tsaryov Is Shot Twice in Crimea

    • It is a difficult moment for Ukraine in the war: the counteroffensive has petered out, Russian forces have started successful offensives in Avdiivka, Kupyansk and other places, foreign aid is starting to dry up with the emergence of the conflict in the Middle East.
    • At this crucial moment of the struggle, Kiev regime resorts to their old expedient: political assassinations.
    • It is common knowledge that Ukrainians maintain a website called Myrotvorets (‘Peacemaker’), a vast ‘unofficial’ (but sanctioned) database of people considered to be enemies of the country.
    • To be listed there as a ‘traitor to the motherland’ is to be marked for potential assassination.
    • That was the case of former Ukrainian lawmaker Oleg Tsaryov, a pro-Russian figure reportedly tasked to lead Kyiv after Russia’s invasion.
    • Tsaryov was shot and wounded in a late-night attack, family and officials said on Friday.
    • Reutersreported:
    • Several pro-war Russian figures in the ‘peacemaker’ database have been assassinated since the start of the war.
    • The list includes journalistDarya Dugina, war blogger Vladlen Tatarskyand former submarine commanderStanislav Rzhitsky.
    • The Guardianreported:

    Source: thegatewaypundit.com

    MORE – German police union warns about "life-threatening" unrest in the country: "The police are being challenged like never before in post-war history." pic.twitter.com/VRbdo1JLEk

    — Disclose.tv (@disclosetv) October 30, 2023

    Pistorius sees danger of war in Europe — ZDF pic.twitter.com/SY3iK5doGT

    — Disclose.tv (@disclosetv) October 29, 2023

    NOW – Israel's Defence Minister to Hamas: "Die or surrender." pic.twitter.com/oCULYRz06K

    — Disclose.tv (@disclosetv) October 30, 2023

    "Should the Palestinian group Hamas be considered a terrorist organization?"

    Yes-
    DEM: 70%
    IND: 78%
    GOP: 85%
    All Voters: 78%

    Story – https://t.co/WbgmFBi8Yo https://t.co/ifUzkILcEJ

    — Rasmussen Reports (@Rasmussen_Poll) October 29, 2023

    CRISIS: The terrorist war against Israel has exposed that there are a large number of American left-wing activists and members of Congress who will promote, defend, and excuse the murder, rape, kidnapping, etc. of their political enemies.

    — Tom Fitton (@TomFitton) October 29, 2023

    False Flags

    Macron Announces Legislation to Enshrine ‘Freedom of Abortion’ in French Constitution
    • President Emmanuel Macron announced that his government will introduce legislation this week to enshrine the “freedom” to have an abortion into the French Constitution.
    • Vowing to introduce legislation this week with the hopes of presenting a bill to the Council of Ministers by the end of the year, President Macron declared on social media on Sunday: “In 2024, the freedom of women to have an abortion will be irreversible.”
    • Macron first committed to include abortion access in the Constitution on March 8th, which marks the communist holiday International Women’s Day.
    • Although the inclusion of the “freedom” to have an abortion would likely have minimal impact on the current legal status of abortion in the country, with the practice already being legal, it could serve as an impediment to future governments seeking to enact restrictions or place limits on abortions.
    • There was some debate within the government about the specific language of the amendment, with some demanding that the text guarantee the “right” to an abortion.
    • The government ultimately decided to propose a “freedom of abortion”, however, theÉlyséeclaimed that it is essentially a distinction without a difference given that the Constitution permits “the same constitutional guarantee” to rights and freedoms.

    Source: breitbart.com

    This is from the CVS on H Street in Washington DC.

    Due to the out-of-control theft, they have now put away almost all their items and just have photographs of what is in stock.

    You press the button and the sales associate gets you what you need.

    I was in Barcelona, Spain a few… pic.twitter.com/jOif99w77d

    — Joey Mannarino (@JoeyMannarinoUS) October 27, 2023

    Q

    • It is “very likely” that President Biden has committed impeachable offenses, according to Speaker Mike Johnson, who waselected to the office on Wednesdayafter three weeks of Republican turmoil.
    • In September, then-SpeakerKevin McCarthylaunched aformal impeachment inquiry into Biden. It focused on whether the president was ever influenced by the business dealings of his sonHunter Biden, potentially setting the stage for an impeachment trial. McCarthy said the president faced “allegations of abuse of power, obstruction and corruption,” warranting further investigation.

    Source: newsweek.com

    WHY NOW? SNL Lightly Roasts Biden Over His Age in Halloween Skit with Cameo From Christopher Walken (VIDEO)

    • Saturday Night Live lightly roasted Joe Biden over his age this week in a Halloween skit

    Source: thegatewaypundit.com

    Michelle Obama Looks Disheveled in ‘Get Out the Vote’ Pitch Amid Rumors of Possible Presidential Bid

    • Michelle Obama looked disheveled in a ‘get out the vote’ pitch on Friday amid rumors of a possible presidential bid.
    • Prominent political figures have recently predicted Michelle Obama will be the Democrat presidential nominee in 2024.
    • The majority of Democrat voters believe Joe Biden is too old to serve a second term so many are now speculating he will be replaced with California Governor Gavin Newsom… or perhaps Michelle Obama.
    • Ted Cruzsaid last monththe Democrats are going to pull a surprise by drafting Michelle Obama to take Joe Biden’s place for the 2024 race.
    • “Here’s the scenario that I think is perhaps most likely, and most dangerous,” Senator Cruz said on his ‘Verdict with Ted Cruz’ podcast. “In August of 2024, the Democrat kingmakers jettison Joe Biden and parachute in Michelle Obama.”
    • Former Alaska Governor Sarah PalinsaidMichelle Obama will be the Democrat Party’s 2024 nominee.
    • “Don’t be surprised,” Palin said last week. “But I still say it’ll be Michelle O’ #2024Election”
    • “Biden’s out,” she said.
    • Barack Obama was spotted leaving Funke restaurant in Beverly Hills earlier this month. He stayed silent after he was asked if his wife Michelle is running for president.

    Source: thegatewaypundit.com

    DISGUSTING! Dirty Leftist Attorneys Play Video of Trump on Jan. 6 to Open Colorado Case to Remove Trump from Ballot – REFUSE TO PLAY His Words Encouraging Supporters to be Peaceful (VIDEO)

    • The dirty left was up to their old tricks again today.
    • Radical leftist attorneys in Colorado opened their argument to toss President Trump from the ballot in the state.
    • During their opening remarks, these far-left attorneys shared two clips of President Trump’s speech at the Ellipse to a million supporters on January 6, 2021.
    • They insist President Trump started a violent riot.
    • Here is the video they would not play in court – President Trump telling supporters to be PEACEFUL!

    • The attorneys hid that from the court.

    Source: thegatewaypundit.com

    Obama-Appointed Judge Chutkan Reinstates Gag Order on President Trump

    • Earlier this month Obama- appointed Judge Tanya Chutkan initiated a gag order on President Donald Trump, the leading presidential candidate in the 2024 presidential election.
    • This is complete lawlessness. Even the far-left ACLU laterfiled a briefarguing the that an overly-broad gag order imposed on Donald J. Trump in an ongoing election interference case violates the First Amendment.
    • Chutkan’s initial gag order on Trump wasworse than we thought.
    • According to Chutkan’s gag order, Trump cannot criticize Special Counsel Jack Smith or any of his prosecutors – even if Trump is telling the truth!

    Source: thegatewaypundit.com

    • BOTH Parties in the Polls. Few can believe this is happening, but I will appeal. How can they tell the leading candidate that he, and only he, is seriously restricted from campaigning in a free and open manner? It will not stand!

    Fact (and Legal) Check: True.

    Biden special counsel Jack Smith and Obama DC Judge Tanya Chutkan are blatantly violating Trump's constitutional rights.

    A criminal defendant—more than anyone—must have the right to criticize the prosecutor, judge, court staff, witnesses, and… pic.twitter.com/KgBr34J9jQ

    — 🇺🇸 Mike Davis 🇺🇸 (@mrddmia) October 30, 2023

    and process. This gag order is an obviously illegal prior restraint on free speech. It’s un-American.

    • Trump has appeared to threaten President Joe Bidenwith prosecution in a post on his social media platform,Truth Social. The former president raged against his successor over the various lawsuits and indictments he is facing, and warned Biden “the same can happen to you.”

    Source: newsweek.com

    “As president, I will be creating a Truth and Reconciliation Commission to shed sunlight on every dark and rotten corner of Washington, DC.” — President Trump in Sioux City, Iowa pic.twitter.com/spe3uU1q0Z

    — RSBN 🇺🇸 (@RSBNetwork) October 29, 2023

    TAKE A LISTEN

    He can do this because they already set the path

    💥Trump confirms 2 major things in this clip.

    1) They are the ones that are really under investigation. 💥 (Hint.. They already know) "We are just trying to figure out how much" money China pays Joe directly.

    2) They have it all. 💥 "All the facts we have. And you'll be… https://t.co/XccHBfdQyC pic.twitter.com/WmZnlDWxm5

    — Joe Rambo (@BrainStorm_Joe) October 30, 2023

    TAKE A LISTEN

    “We will do things that nobody thought were even possible”: President Trump closes out remarks in Sioux City, Iowa pic.twitter.com/XPtlENZ3cb

    — RSBN 🇺🇸 (@RSBNetwork) October 29, 2023

    pic.twitter.com/Zp0ak5tAfu

    — Dan Scavino Jr.🇺🇸🦅 (@DanScavino) October 30, 2023

    Confirmed,[DS] Set The Path&Under Investigation,We Can Now Do Things That Were Not Possible – Ep. 3200 (2024)

    FAQs

    Why is electron removed from 4s before 3d? ›

    The electrons are removed from the 4s orbital before the 3d orbital. This is because the effective nuclear charge (Zeff) is more for 3d electrons than 4s electrons. As Zeff is more for 3d electrons they are tightly bound to nucleus than that of 4s electrons. So that's why we remove 4s electrons before 3d electrons.

    Why does d orbital start at 3? ›

    Because that is the structure in which the balance of repulsions and the size of the energy gap between the 3d and 4s orbitals happens to produce the lowest energy for the system.

    Why is 4s2 before 3d10? ›

    A simple rule to follow: Filling up of orbitals is dependent on orbital energy while removal of electrons from orbitals is dependent on orbital location. 4s has a lower energy than 3d. So it gets filled up first.

    Is 4s higher than 3d? ›

    The 4s subshell is lower in energy than the 3d subshell, so it fills up first. The 4s becomes higher in energy after filling up, so if you ionize the atom, electrons are lost from the 4s subshell before the 3d subshell.

    Does 4s always fill before 3d? ›

    You always fill 4s orbital first, except with Cr and Cu. 4s has a lower energy so it fills before 3d.

    Why electrons enter into 4s but not 3d after filling the 3p orbital? ›

    Explanation: Because according to Aufbau's principle,electrons get filled in the increasing level of energy of the orbitals,after 3p, among 4s(n+l=4) and 3d(n+l=5) energy of 4s is lower due to lower (n+l) value, therefore electrons tend to fill in the 4s orbital first.

    Does 3d exist in chemistry? ›

    The 3d orbital is lower energy after element 20 (Sc) because of electron shielding. Electrons are added the 4s shell first because it is more stable, but when electrons are added to the 3d orbital, shielding becomes a factor.

    Why is there no 1p or 2d orbital? ›

    The principal quantum number n must be larger than the angular momentum quantum number l. Thus, for n = 1, only l = 0 gives a valid wave function, for n = 2, you can only have l = 0, 1 (s and p), and so on. So this is why, we only have s orbitals in the first shell, 1p orbital does not exist.

    Why does it start at 3d and not 4d? ›

    This is because the 4s orbital is at a lower energy level than the 3d orbital. Therefore, according to the Aufbau principle, the 4s orbital is filled first. This means that the first two elements of the fourth period, potassium (K) and calcium (Ca), have their outermost electrons in the 4s orbital.

    Why is 5s filled before 4d? ›

    Even though 5s orbitals have a higher principal quantum number than 4d orbitals, (n = 5 compared to n = 4), they're actually lower in energy. As a result, 5s orbitals are always filled before 4d orbitals. Similarly, 6s orbitals are lower in energy than 5d orbitals, so 6s orbitals are always filled first.

    What would come after 3d10? ›

    Even though the subshells are filled according to energy level, the notation is often written out in numerical order. 1s2,2s2,2p6,3s2,3p6,3d10,4s2,4p6…..

    Is there anything higher than 3d? ›

    Four-dimensional space (4D) is the mathematical extension of the concept of three-dimensional space (3D).

    Why is 5d filled before 4f? ›

    Why is 5d filled before 4f in lanthanum? According to the aufbau rule, the orbital with lower energy always gets filled by electrons first. So one might expect that electrons will go into shell 4f before 5d. However, any orbital containing only 1 electron is inherently unstable.

    What is the n/l rule? ›

    The (n+l) rule, also known as the Aufbau principle or Aufbau sequence, determines the energy of all atomic orbitals. The rule says that the orbital having a lower value of (n+l) is filled first. If two orbitals have the same n+l, the one with lower n is filled first.

    Why do electrons enter the 4s orbital before entering the 3d orbital? ›

    Hence, it is clear that the 4s orbital comprises lesser energy as compared to 3d orbital and thus, the electrons enter 4s orbital before entering the 3d orbitals.

    Why are electrons removed from 5s before 4d? ›

    The electrons will be removed from the highest energy shell in the neutral configuration. This means that electrons will be removed from the 4s subshell before any electrons are removed from the 3d subshell, and similarly electrons will be removed from the 5s subshell before they are removed from the 4d subshell.

    Why do electrons enter the 4s orbital before entering the 3d orbital quizlet? ›

    This is because electrons in the 4s subshell have lower potential energy than those in the 3d subshell, and the orbital filling sequence is based on the lowest potential energy of electrons in each orbital.

    Why does the periodic table go from 4s to 3d? ›

    So 4s is lower in energy so fills first. After calcium the 3d orbital falls below the 4s in terms of energy. This means the 4s electrons are lost first in chemical reactions and define the atomic radius of the atom.

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